Fundamental physical behaviors of materials at the nanoscale level are crucial when local aspects govern the macroscale performance of nanocomposites, e.g., interface and surface phenomena. Because of the increasing interest in biopolymer nanocomposite coatings for many different applications (e.g., optical devices, displays/screens, and packaging), this work investigates the potential of nanoindentation as a method for clarifying the interplay between distinct phases (i.e., organic and inorganic) at local level in thin biopolymer films loaded with nanoparticles. The nanomechanical features of pullulan nanocomposite coatings laid on polyethylene terephthalate (PET) were quantified in terms of elastic modulus (E), hardness (H), and creep (C) through an instrumented indentation test composed of a loading-holding-unloading cycle. Colloidal silica (CS) and cellulose nanocrystals (CNCs) were used as spherical and rod-like nanoparticles, respectively. An overall reinforcing effect was shown for all nanocomposite coatings over the pristine (unfilled) pullulan coating. A size effect was also disclosed for the CS-loaded surfaces, with the highest E value recorded for the largest particles (8.19 ± 0.35 GPa) and the highest H value belonging to the smallest ones (395.41 ± 25.22 MPa). Comparing CS and CNCs, the addition of spherical nanoparticles had a greater effect on the surface hardness than cellulose nanowhiskers (353.50 ± 83.52 MPa and 321.36 ± 43.26 MPa, respectively). As for the elastic modulus, the addition of CS did not provide any improvement over both the bare and CNC-loaded pullulan coatings, whereas the coating including CNCs exhibited higher E values (p < .05). Finally, CS-loaded pullulan coatings were the best performing in terms of C properties, with an average indentation depth of 16.5 ± 1.85 nm under a load of ∼190 μN. These results are discussed in terms of local distribution gradients, surface chemistry of nanoparticles, and how nanoparticle aggregation occurred in the dry nanocomposite coatings.
Mechanical behavior of biopolymer composite coatings on plastic films by depth-sensing indentation : a nanoscale study / C. Rovera, C.A. Cozzolino, M. Ghaani, D. Morrone, R.T. Olsson, S. Farris. - In: JOURNAL OF COLLOID AND INTERFACE SCIENCE. - ISSN 0021-9797. - 512(2018 Feb 15), pp. 638-646.
|Titolo:||Mechanical behavior of biopolymer composite coatings on plastic films by depth-sensing indentation : a nanoscale study|
ROVERA, CESARE (Primo)
FARRIS, STEFANO (Ultimo) (Corresponding)
|Parole Chiave:||Aggregation; Biopolymer; Cellulose nanocrystals (CNCs); Coating; Interface; Nanocomposite; Nanoindentation; Phase separation; Pullulan; Surface|
|Settore Scientifico Disciplinare:||Settore AGR/15 - Scienze e Tecnologie Alimentari|
Settore ING-IND/22 - Scienza e Tecnologia dei Materiali
|Progetto:||PIANO DI SOSTEGNO ALLA RICERCA 2015-2017 - LINEA 2 "DOTAZIONE ANNUALE PER ATTIVITA' ISTITUZIONALE"|
|Data di pubblicazione:||15-feb-2018|
|Data ahead of print / Data di stampa:||31-ott-2017|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1016/j.jcis.2017.10.108|
|Appare nelle tipologie:||01 - Articolo su periodico|