The reaction of [Re2(CO)10] with OH- gives first [Re2H(CO)9]- and then, under more drastic conditions, the novel anion [Re2H2(CO)8]2-, which can be reversibly protonated to give [Re2H2(μ-H)(CO)8]-, whose structure has been elucidated by a X-ray investigation. Variable-temperature NMR spectra indicate that both the new hydrido carbonylates are fluxional in solution. © 1987 American Chemical Society.
New hydrido-carbonyl rhenates by reduction of [Re2(CO)10] with bases. X-ray crystal structure of the anion [Re2H2(μ-H)(CO)8] / T. Beringhelli, G. D'Alfonso, L. Ghidorsi, G. Ciani, A. Sironi, H. Molinari. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 6:6(1987), pp. 1365-1367.
Titolo: | New hydrido-carbonyl rhenates by reduction of [Re2(CO)10] with bases. X-ray crystal structure of the anion [Re2H2(μ-H)(CO)8] |
Autori: | BERINGHELLI, TIZIANA (Primo) D'ALFONSO, GIUSEPPE (Secondo) SIRONI, ANGELO AGOSTINO DANIELE (Penultimo) |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica |
Data di pubblicazione: | 1987 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1021/om00149a044 |
Appare nelle tipologie: | 01 - Articolo su periodico |