The redox condensation between [Pt3(CO)6n]2- (n ≈ 10) and rhenium carbonyl anions gives two novel mixed-metal species, [PtRe3(μ-H)(CO)13]2- and [PtRe4(CO)17]2-, containing a Pt-CO unit interacting with three and four Re(CO)4 moieties, respectively, arranged as a stripe folded around the Pt atom and whose formation confirms the tendency of Re atoms to cluster around Pt, giving structures based on Re2Pt triangles with a low Pt:Re ratio.
Pseudo-raft rhenium-platinum clusters. Synthesis and crystal structure of the anions [PtRe3(μ-H)(CO)13]2- and [PtRe4(CO)17]2-, containing a central Pt atom surrounded by a folded stripe of Re atoms / T. Beringhelli, A. Ceriotti, G. Ciani, G. D'Alfonso, L. Garlaschelli, R. D. Pergola, M. Moret, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - :1(1993), pp. 199-200.
Titolo: | Pseudo-raft rhenium-platinum clusters. Synthesis and crystal structure of the anions [PtRe3(μ-H)(CO)13]2- and [PtRe4(CO)17]2-, containing a central Pt atom surrounded by a folded stripe of Re atoms |
Autori: | BERINGHELLI, TIZIANA (Primo) CERIOTTI, ALESSANDRO UBERTO (Secondo) SIRONI, ANGELO AGOSTINO DANIELE (Ultimo) |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica |
Data di pubblicazione: | 1993 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/DT9930000199 |
Appare nelle tipologie: | 01 - Articolo su periodico |