The novel anions [Re3H3(CO)10(μ-O2CR)]- (R = H, CH3, CF3), obtained by reaction of [Re3H4(CO)10]- with the corresponding carboxylic acids, have been characterized by IR and NMR spectra and by X-ray analysis of the formate and trifluoroacetate derivatives. They contain a triangle of rhenium atoms, with the carboxylate group diaxially bridging on the shorter ReRe edge. © 1982.

Reactions of the unsaturated anion [Re3H4(CO)10]- with carboxylic acids and x-ray characterization of the anions [Re3H3(CO)10(μ-O2CR)]- (R = H, CF3) / T. Beringhelli, G. Ciani, G. D'Alfonso, A. Sironi, M. Freni. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 233:3(1982), pp. C46-C46-C50.

Reactions of the unsaturated anion [Re3H4(CO)10]- with carboxylic acids and x-ray characterization of the anions [Re3H3(CO)10(μ-O2CR)]- (R = H, CF3)

T. Beringhelli;G. Ciani;G. D'Alfonso;A. Sironi;
1982

Abstract

The novel anions [Re3H3(CO)10(μ-O2CR)]- (R = H, CH3, CF3), obtained by reaction of [Re3H4(CO)10]- with the corresponding carboxylic acids, have been characterized by IR and NMR spectra and by X-ray analysis of the formate and trifluoroacetate derivatives. They contain a triangle of rhenium atoms, with the carboxylate group diaxially bridging on the shorter ReRe edge. © 1982.
Settore CHIM/03 - Chimica Generale e Inorganica
JOURNAL OF ORGANOMETALLIC CHEMISTRY
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/185641
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