The carbido cluster anion [Re7C(CO)21]3- reacts with compounds containing metals, M, of Group IB, namely AuClPPh3, (AgClPPh3)4, AgBF4 and [Cu(NCMe)4]PF6, to give adducts exhibiting a Re7M skeleton, of trans-bicapped octahedral geometry, as demonstrated by the X-ray investigation of the [Re7AgC(CO)212Br]5- anion. © 1985.
Reactions of the carbido cluster anion [Re7C(CO)21]3- with group IB metals: X-ray crystal structure of the novel heterometallic carbide [Re7AgC(CO)212Br]5 / T. Beringhelli, G. D'Alfonso, M. Freni, G. Ciani, A. Sironi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 295:1(1985), pp. c7-c7-c10.
Titolo: | Reactions of the carbido cluster anion [Re7C(CO)21]3- with group IB metals: X-ray crystal structure of the novel heterometallic carbide [Re7AgC(CO)212Br]5 |
Autori: | BERINGHELLI, TIZIANA (Primo) D'ALFONSO, GIUSEPPE (Secondo) CIANI, GIANFRANCO MARIA (Penultimo) SIRONI, ANGELO AGOSTINO DANIELE (Ultimo) |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica |
Data di pubblicazione: | 1985 |
Rivista: | |
Tipologia: | Article (author) |
Appare nelle tipologie: | 01 - Articolo su periodico |