The carbido cluster anion [Re7C(CO)21]3- reacts with compounds containing metals, M, of Group IB, namely AuClPPh3, (AgClPPh3)4, AgBF4 and [Cu(NCMe)4]PF6, to give adducts exhibiting a Re7M skeleton, of trans-bicapped octahedral geometry, as demonstrated by the X-ray investigation of the [Re7AgC(CO)212Br]5- anion. © 1985.
Reactions of the carbido cluster anion [Re7C(CO)21]3- with group IB metals: X-ray crystal structure of the novel heterometallic carbide [Re7AgC(CO)212Br]5 / T. Beringhelli, G. D'Alfonso, M. Freni, G. Ciani, A. Sironi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 295:1(1985), pp. c7-c7-c10.
Reactions of the carbido cluster anion [Re7C(CO)21]3- with group IB metals: X-ray crystal structure of the novel heterometallic carbide [Re7AgC(CO)212Br]5
T. BeringhelliPrimo
;G. D'AlfonsoSecondo
;G. CianiPenultimo
;A. SironiUltimo
1985
Abstract
The carbido cluster anion [Re7C(CO)21]3- reacts with compounds containing metals, M, of Group IB, namely AuClPPh3, (AgClPPh3)4, AgBF4 and [Cu(NCMe)4]PF6, to give adducts exhibiting a Re7M skeleton, of trans-bicapped octahedral geometry, as demonstrated by the X-ray investigation of the [Re7AgC(CO)212Br]5- anion. © 1985.
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