Partial fragmentation of [Re7C(CO)21]3-, by reaction with I2 in MeCN under CO atmosphere, affords the title compound, which contains a carbide atom at the centre of a tetrahedrally distorted square of rhenium atoms.

A new metallic environment for carbon in a carbido metal cluster: X-ray crystal structure of the anion [Re4C(CO)15I] / T. Beringhelli, G. Ciani, G. D'Alfonso, A. Sironi, M. Freni. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :14(1985), pp. 978-979.

A new metallic environment for carbon in a carbido metal cluster: X-ray crystal structure of the anion [Re4C(CO)15I]

T. Beringhelli;G. Ciani;G. D'Alfonso;A. Sironi;
1985

Abstract

Partial fragmentation of [Re7C(CO)21]3-, by reaction with I2 in MeCN under CO atmosphere, affords the title compound, which contains a carbide atom at the centre of a tetrahedrally distorted square of rhenium atoms.
Settore CHIM/03 - Chimica Generale e Inorganica
JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/184073
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