Reaction of [Re3(μ-H)4(CO)10]- with NOBF4 in CH2CI2 gives the [Re 3(μ-H)3(CO)102(μ4- η2-NO)]- anion, containing a nitrosyI group which holds together two triangular cluster moieties by bridging one edge of each triangle through both the N and O atoms.
A novel co-ordination mode of nitric oxide. Synthesis and crystal structure of the [Re3(μ-H)3(CO)10 2(μ4-η2-NO)]- anion / T. Beringhelli, G. Ciani, G. D'Alfonso, H. Molinari, A. Sironi, M. Freni. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :20(1984), pp. 1327-1329. [10.1039/C39840001327]
A novel co-ordination mode of nitric oxide. Synthesis and crystal structure of the [Re3(μ-H)3(CO)10 2(μ4-η2-NO)]- anion
T. BeringhelliPrimo
;G. CianiSecondo
;G. D'Alfonso;A. SironiPenultimo
;
1984
Abstract
Reaction of [Re3(μ-H)4(CO)10]- with NOBF4 in CH2CI2 gives the [Re 3(μ-H)3(CO)102(μ4- η2-NO)]- anion, containing a nitrosyI group which holds together two triangular cluster moieties by bridging one edge of each triangle through both the N and O atoms.
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