Total synthesis of aloperine and 6-epi-aloperine is reported. The crucial steps of the synthetic strategy are an aza-annulation reaction and an intermolecular Diels-Alder reaction. The synthetic plan proceeds from commercially available piperidine-2-ethanol.
Concise total synthesis of (+/-)-aloperine and 6-epi-aloperine / D. Passarella, M. Angoli, A. Giardini, G. Lesma, A. Silvani, B. Danieli. - In: ORGANIC LETTERS. - ISSN 1523-7060. - 4:17(2002), pp. 2925-2928.
Concise total synthesis of (+/-)-aloperine and 6-epi-aloperine
D. PassarellaPrimo
;G. Lesma;A. Silvani;B. DanieliUltimo
2002
Abstract
Total synthesis of aloperine and 6-epi-aloperine is reported. The crucial steps of the synthetic strategy are an aza-annulation reaction and an intermolecular Diels-Alder reaction. The synthetic plan proceeds from commercially available piperidine-2-ethanol.
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