A stereocontrolled total synthesis of the title compound is described, starting from enantiopure intermediates. Two alternative strategies have been developed to ensure the critical formation of the nine-membered ring of 3. (C) 2000 Elsevier Science Ltd. All rights reserved.
Indole alkaloids by a chemoenzymatic approach: two convergent routes for the first enantioselective synthesis of (+)-20R-15,20-dihydrocleavamine / B. Danieli, G. Lesma, D. Passarella, A. Silvani. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 41:18(2000), pp. 3489-3492.
Indole alkaloids by a chemoenzymatic approach: two convergent routes for the first enantioselective synthesis of (+)-20R-15,20-dihydrocleavamine
B. DanieliPrimo
;G. LesmaSecondo
;D. PassarellaPenultimo
;A. SilvaniUltimo
2000
Abstract
A stereocontrolled total synthesis of the title compound is described, starting from enantiopure intermediates. Two alternative strategies have been developed to ensure the critical formation of the nine-membered ring of 3. (C) 2000 Elsevier Science Ltd. All rights reserved.
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