Synthesis of 3-oxo-14,15-dihydroandranginine (3) is detailed based on Diels-Alder reaction of 5-ethenyl-N-[[(tert-butyldimethylsilyl)oxy]ethyl]-3,4-dihyropyri-din-2-one (11b) and methyl N-(p-methoxybenzensulfonyl)indole-2-(2-propenoate (9). This represents the first synthesis of the skeleton of(+/-)-andranginine 1.

Diastereoselective synthesis of 3-oxo-14,15-dihydroandranginine / B. Danieli, G. Lesma, M. Martinelli, D. Passarella, A. Silvani. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - 62:19(1997), pp. 6519-6523.

Diastereoselective synthesis of 3-oxo-14,15-dihydroandranginine

B. Danieli
Primo
;
G. Lesma
Secondo
;
D. Passarella
Penultimo
;
A. Silvani
Ultimo
1997

Abstract

Synthesis of 3-oxo-14,15-dihydroandranginine (3) is detailed based on Diels-Alder reaction of 5-ethenyl-N-[[(tert-butyldimethylsilyl)oxy]ethyl]-3,4-dihyropyri-din-2-one (11b) and methyl N-(p-methoxybenzensulfonyl)indole-2-(2-propenoate (9). This represents the first synthesis of the skeleton of(+/-)-andranginine 1.
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/177277
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