Desymmetrization of dimethyl meso-piperidine-3,5-dicarboxylates 3a-c with pig liver esterase (PLE), lipase from Candida cylindracea (CCL) and porcine pancreatic lipase (PPL) is described. The enantioselectivities of the enzymatic transformations and the absolute configurations of the resulting half-esters 2a-c were determined.
Stereoselective enzymatic hydrolysis of dimethyl meso-piperidine-3,5-dicarboxylates / B. Danieli, G. Lesma, D. Passarella, A. Silvani. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 7:2(1996), pp. 345-348. [10.1016/0957-4166(96)00002-X]
Stereoselective enzymatic hydrolysis of dimethyl meso-piperidine-3,5-dicarboxylates
B. DanieliPrimo
;G. LesmaSecondo
;D. PassarellaPenultimo
;A. SilvaniUltimo
1996
Abstract
Desymmetrization of dimethyl meso-piperidine-3,5-dicarboxylates 3a-c with pig liver esterase (PLE), lipase from Candida cylindracea (CCL) and porcine pancreatic lipase (PPL) is described. The enantioselectivities of the enzymatic transformations and the absolute configurations of the resulting half-esters 2a-c were determined.
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