A new synthesis of macrolactones bearing a cyclopropyl ring condensed to the macrocycle is reported via a cyclization-release strategy making use of solid-phase supported stabilized sulfur ylides.
Cyclative cleavage via solid-phase supported stabilized sulfur ylides: synthesis of macrocyclic lactones / E. La Porta, U. Piarulli, F. Cardullo, A. Paio, S. Provera, P. Seneci, C.M.A. Gennari. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 43:5(2002), pp. 761-766. [10.1016/S0040-4039(01)02258-4]
Cyclative cleavage via solid-phase supported stabilized sulfur ylides: synthesis of macrocyclic lactones
P. SeneciPenultimo
;C.M.A. GennariUltimo
2002
Abstract
A new synthesis of macrolactones bearing a cyclopropyl ring condensed to the macrocycle is reported via a cyclization-release strategy making use of solid-phase supported stabilized sulfur ylides.
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