An intermolecular aldol reaction of 20S-camptothecin-7-aldehyde in the presence of strong bases affords an unusual dimeric compound, the structure and stereochemistry of which was assigned on the basis of NMR analysis and MM2 calculations.
An unusual dimer of camptothecin-7-aldehyde / S. Dallavalle, L. Merlini, L. Musso. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 45:42(2004), pp. 7879-7881.
An unusual dimer of camptothecin-7-aldehyde
S. Dallavalle;L. Merlini;L. Musso
2004
Abstract
An intermolecular aldol reaction of 20S-camptothecin-7-aldehyde in the presence of strong bases affords an unusual dimeric compound, the structure and stereochemistry of which was assigned on the basis of NMR analysis and MM2 calculations.
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