Equilibrium phenomena are characterized by time symmetry. Thermodynamic fluctuations are also time-symmetric at equilibrium. Conversely, diffusion of a solute in a liquid in the presence of a gradient is a nonequilibrium phenomenon, which gives rise to long-range fluctuations with amplitude much larger than the equilibrium one for small enough wave number. In the case of diffusion in binary mixtures such fluctuations are time-symmetric, notwithstanding the fact that they are generated by a nonequilibrium condition. In this paper, we investigate diffusion of two solutes in a ternary liquid mixture by means of fluctuating hydrodynamics theory. We show that the time-cross-correlation function of the concentrations is not time-symmetric, hence showing that time symmetry is violated for such nonequilibrium fluctuations. We discuss the feasibility of experiments aimed at the detection of the asymmetry of the cross-correlation function of nonequilibrium concentration fluctuations in ternary mixtures, as envisaged in the Giant Fluctuations (NEUF-DIX) microgravity project of the European Space Agency.
Asymmetric time-cross-correlation of nonequilibrium concentration fluctuations in a ternary liquid mixture / D. Brogioli, F. Croccolo, A. Vailati. - In: PHYSICAL REVIEW. E. - ISSN 2470-0045. - 99:5(2019), pp. 053115.1-053115.10.
Titolo: | Asymmetric time-cross-correlation of nonequilibrium concentration fluctuations in a ternary liquid mixture |
Autori: | CROCCOLO, FABRIZIO (Secondo) VAILATI, ALBERTO (Ultimo) |
Settore Scientifico Disciplinare: | Settore FIS/03 - Fisica della Materia |
Progetto: | ESA Topical Team Giant Fluctuations |
Data di pubblicazione: | 2019 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1103/PhysRevE.99.053115 |
Appare nelle tipologie: | 01 - Articolo su periodico |
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