New polynuclear coordination species containing the ditopic bis(1- imidazolyl)methane (Bim) ligand have been prepared as microcrystalline powders and structurally characterized by ab initio X-ray powder diffraction methods. [Bim(Me2SnCl2)]n (1), [Bim(nBu2SnCl2)]n (3), [Bim(Ph2SnCl2)]n (4), [Bim(MeSnCl3)]n (5), and [Bim(PhSnCl3)]n (6) all contain 1D chains with octahedral tin atoms with trans N-Sn-N linkages (but 4, which displays a cis N-Sn-N linkage). Their thermodiffractometric analysis allowed the estimation of the linear thermal expansion coefficients and strain tensors derived there from. The potential-energy surface of the free Bim ligand (as defined by two torsional degrees of freedom about the two N-CH2 bonds), eventually controlling the length of the repeating unit (polymer elongation), has been estimated using molecular mechanics and correlated with experimental observations.
Structural and Thermodiffractometric Analysis of Coordination Polymers. Part 1., Tin Derivatives of the Bim ligand [Bim ) Bis(1-imidazolyl)methane]) / N. Masciocchi, C. Pettinari, E. Alberti, R. Pettinari, C. Di Nicola, A. Figini Albisetti, A. Sironi. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - 46:25(2007), pp. 10491-10500. [10.1021/ic701530c]
Structural and Thermodiffractometric Analysis of Coordination Polymers. Part 1., Tin Derivatives of the Bim ligand [Bim ) Bis(1-imidazolyl)methane])
A. Figini AlbisettiPenultimo
;A. SironiUltimo
2007
Abstract
New polynuclear coordination species containing the ditopic bis(1- imidazolyl)methane (Bim) ligand have been prepared as microcrystalline powders and structurally characterized by ab initio X-ray powder diffraction methods. [Bim(Me2SnCl2)]n (1), [Bim(nBu2SnCl2)]n (3), [Bim(Ph2SnCl2)]n (4), [Bim(MeSnCl3)]n (5), and [Bim(PhSnCl3)]n (6) all contain 1D chains with octahedral tin atoms with trans N-Sn-N linkages (but 4, which displays a cis N-Sn-N linkage). Their thermodiffractometric analysis allowed the estimation of the linear thermal expansion coefficients and strain tensors derived there from. The potential-energy surface of the free Bim ligand (as defined by two torsional degrees of freedom about the two N-CH2 bonds), eventually controlling the length of the repeating unit (polymer elongation), has been estimated using molecular mechanics and correlated with experimental observations.Pubblicazioni consigliate
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