(E)-2-methyl- and (E)-3-methyl-2,4-pentadien-1-ols are reduced to (S)-2-methyl- and (S)-3-methyl-4-penten-1-ols, respectively, using baker's yeast as a regio- and stereoselective reagent. This microbiological conversion provides an efficient route to bifunctional and enantiomerically pure C6-building blocks containing the C' -CH(Me )-C'' grouping.
Regio- and stereoselective hydrogenation of methyl substituted pentadien-1-ols by baker's yeast / P. Gramatica, P. Manitto, D. Monti, G. Speranza. - In: TETRAHEDRON. - ISSN 0040-4020. - 44:4(1988), pp. 1299-1304. [10.1016/S0040-4020(01)85910-X]
Regio- and stereoselective hydrogenation of methyl substituted pentadien-1-ols by baker's yeast
P. Manitto;G. Speranza
1988
Abstract
(E)-2-methyl- and (E)-3-methyl-2,4-pentadien-1-ols are reduced to (S)-2-methyl- and (S)-3-methyl-4-penten-1-ols, respectively, using baker's yeast as a regio- and stereoselective reagent. This microbiological conversion provides an efficient route to bifunctional and enantiomerically pure C6-building blocks containing the C' -CH(Me )-C'' grouping.
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