The (S)-forms of (E)-3,7-dimethyl-2-octene-1,8-diol (secreted by male danaid butterflies) and of (E)-3,7-dimethyl-2-octene-1,8-dioic acid (a pheromone of the azuki bean weevil) were synthesized via stereoselective hydrogenation by baker’s yeast of the carbonyl activated double bond of achiral precursors.
Baker yeast hydrogenation of carbonyl activated double-bonds-enantioselective synthesis of the (S)-form of the dihydroterpenediol secreted by danaus-chrysippus and of a pheromone of callosobruchus-chinensis L / P. Gramatica, G. Giardina, G. Speranza, P. Manitto. - In: CHEMISTRY LETTERS. - ISSN 0366-7022. - 9(1985), pp. 1395-1398. [10.1246/cl.1985.1395]
Baker yeast hydrogenation of carbonyl activated double-bonds-enantioselective synthesis of the (S)-form of the dihydroterpenediol secreted by danaus-chrysippus and of a pheromone of callosobruchus-chinensis L
G. Speranza;P. Manitto
1985
Abstract
The (S)-forms of (E)-3,7-dimethyl-2-octene-1,8-diol (secreted by male danaid butterflies) and of (E)-3,7-dimethyl-2-octene-1,8-dioic acid (a pheromone of the azuki bean weevil) were synthesized via stereoselective hydrogenation by baker’s yeast of the carbonyl activated double bond of achiral precursors.
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1985 Chem Lett 1395.pdf
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