The [Re2(-trz-N1:N2)2(-OH)(CO)6]- (trz = 1,2,4-triazolate) organometallic anion reacts with Ag+ to afford a 2D organometallic/coordination network, [Ag{Re2(3-trz-N1:N2:N4)2(3-OH)(CO)6}]n4nCH3OH, which shows dynamic structural changes triggered by solid-liquid guest exchange processes.
[Re2(mu-1,2,4-triazolate)2(mu-OH)(CO)6]-: a novel metalloligand for the construction of flexible porous coordination networks / E. Barea, A. Rodríguez-Diéguez, J.A.R. Navarro, G. D’Alfonso, A. Sironi. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - :14(2008), pp. 1825-1827.
[Re2(mu-1,2,4-triazolate)2(mu-OH)(CO)6]-: a novel metalloligand for the construction of flexible porous coordination networks
G. D’AlfonsoPenultimo
;A. SironiUltimo
2008
Abstract
The [Re2(-trz-N1:N2)2(-OH)(CO)6]- (trz = 1,2,4-triazolate) organometallic anion reacts with Ag+ to afford a 2D organometallic/coordination network, [Ag{Re2(3-trz-N1:N2:N4)2(3-OH)(CO)6}]n4nCH3OH, which shows dynamic structural changes triggered by solid-liquid guest exchange processes.
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