We have synthesized and characterized a series of bis-(phenanthroline) Cu(I) complexes of interest as redox mediators for dye-sensitized solar cells. This study led to the discovery of intriguing anagostic interactions between the hydrogen atom and the copper center as evidenced by X-ray diffraction studies on a single crystal. Remarkably, an anagostic interaction was found between a H atom of a methyl group and a copper site
Intriguing C–H⋯Cu interactions in bis-(phenanthroline)Cu(I) redox mediators for dye-sensitized solar cells / A. Colombo, R. Ossola, M. Magni, D.M. Roberto, D. Jacquemin, C. Castellano, F. Demartin, C. Dragonetti. - In: DALTON TRANSACTIONS. - ISSN 1477-9234. - 47:4(2018), pp. 1018-1022. [10.1039/c7dt04045h]
Intriguing C–H⋯Cu interactions in bis-(phenanthroline)Cu(I) redox mediators for dye-sensitized solar cells
A. Colombo;M. Magni;D.M. Roberto;C. Castellano;F. Demartin
;C. Dragonetti
2018
Abstract
We have synthesized and characterized a series of bis-(phenanthroline) Cu(I) complexes of interest as redox mediators for dye-sensitized solar cells. This study led to the discovery of intriguing anagostic interactions between the hydrogen atom and the copper center as evidenced by X-ray diffraction studies on a single crystal. Remarkably, an anagostic interaction was found between a H atom of a methyl group and a copper site
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