A synthetic approach to sporotricale methylether, a metabolite of the fungus Sporotrichum laxum with inhibitory activity against Helicobacter pylori, is described. The synthesis relies on the condensation of 13-hydroxy-10-oxotetradecanal, prepared via reaction of a sulfone-activated moiety with valerolactone, with diethyl 3,5-dimethoxyphthalide-7-phosphonate.
A synthetic approach to sporotricale methylether / S. Dallavalle, R. Nannei, L. Merlini, A. Bava, G. Nasini. - In: SYNLETT. - ISSN 0936-5214. - 17(2005 Oct 17), pp. G22305ST.2676-G22305ST.2678. [10.1055/s-2005-917096]
A synthetic approach to sporotricale methylether
S. DallavallePrimo
;R. NanneiSecondo
;L. Merlini;
2005
Abstract
A synthetic approach to sporotricale methylether, a metabolite of the fungus Sporotrichum laxum with inhibitory activity against Helicobacter pylori, is described. The synthesis relies on the condensation of 13-hydroxy-10-oxotetradecanal, prepared via reaction of a sulfone-activated moiety with valerolactone, with diethyl 3,5-dimethoxyphthalide-7-phosphonate.
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