A straightforward synthesis of the C15–C23 fragment of dictyostatin has been achieved by a highly stereoselective Carreira alkynylation between alkyne 1 and aldehyde 2, followed by three chemoselective reductions.
Synthesis of the C15-C23 fragment of dictyostatin using a highly stereoselective Carreira alkynylation / O. Sharon, C. Monti, C. Gennari. - In: TETRAHEDRON. - ISSN 0040-4020. - 63:26(2007), pp. 5873-5878.
Synthesis of the C15-C23 fragment of dictyostatin using a highly stereoselective Carreira alkynylation
C. MontiSecondo
;C. GennariUltimo
2007
Abstract
A straightforward synthesis of the C15–C23 fragment of dictyostatin has been achieved by a highly stereoselective Carreira alkynylation between alkyne 1 and aldehyde 2, followed by three chemoselective reductions.
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