Vibrational circular dichroism, VCD, gives evidence that the carbon monoxide chromophore in a heteroleptic cyclopentadienyl Ru(ii)-carbonyl complex is very sensitive to the chirality of the metal centre and becomes an excellent probe to define the configuration of chiral metal complexes.
VCD spectroscopy as an excellent probe of chiral metal complexes containing a carbon monoxide vibrational chromophore / M. Fusè, G. Mazzeo, G. Longhi, S. Abbate, D. Zerla, I. Rimoldi, A. Contini, E. Cesarotti. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 51:45(2015 Jun 07), pp. 9385-9387.
VCD spectroscopy as an excellent probe of chiral metal complexes containing a carbon monoxide vibrational chromophore
M. FusèPrimo
;D. Zerla;I. Rimoldi;A. ContiniPenultimo
;E. Cesarotti
2015
Abstract
Vibrational circular dichroism, VCD, gives evidence that the carbon monoxide chromophore in a heteroleptic cyclopentadienyl Ru(ii)-carbonyl complex is very sensitive to the chirality of the metal centre and becomes an excellent probe to define the configuration of chiral metal complexes.
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