Vibrational circular dichroism, VCD, gives evidence that the carbon monoxide chromophore in a heteroleptic cyclopentadienyl Ru(ii)-carbonyl complex is very sensitive to the chirality of the metal centre and becomes an excellent probe to define the configuration of chiral metal complexes.

VCD spectroscopy as an excellent probe of chiral metal complexes containing a carbon monoxide vibrational chromophore / M. Fusè, G. Mazzeo, G. Longhi, S. Abbate, D. Zerla, I. Rimoldi, A. Contini, E. Cesarotti. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 51:45(2015 Jun 07), pp. 9385-9387.

VCD spectroscopy as an excellent probe of chiral metal complexes containing a carbon monoxide vibrational chromophore

M. Fusè
Primo
;
D. Zerla;I. Rimoldi;A. Contini
Penultimo
;
E. Cesarotti
2015

Abstract

Vibrational circular dichroism, VCD, gives evidence that the carbon monoxide chromophore in a heteroleptic cyclopentadienyl Ru(ii)-carbonyl complex is very sensitive to the chirality of the metal centre and becomes an excellent probe to define the configuration of chiral metal complexes.
circular-dichroism spectra; absolute-configuration; crystal-structure; transition-metal; sterochemistry; series
Settore CHIM/03 - Chimica Generale e Inorganica
Settore CHIM/06 - Chimica Organica
7-giu-2015
Article (author)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/288769
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