Co- and Cu-based catalysts prepared by flame pyrolysis (FP) technique are proposed as possible substitutes for Ni-based catalysts, very active for the Ethanol Steam Reforming reaction, but showing poor stability towards coke formation when operating at relatively low temperature. The FP method allowed to achieve a partial incorporation of the active phase into the support, leading to high dispersion and lower reducibility. The best results were achieved with 10wt% Co/SiO2, which led to higher activity, good C balance and low CO/CO2 ratio. This was ascribed to the high initial dispersion of Co into the silica matrix, which led to available Co particles well dispersed and stable.
Steam reforming of ethanol over Co and Cu based catalysts / E. Finocchio, G. Ramis, I.G. Rossetti. ((Intervento presentato al 11. convegno Europacat European Congress on Catalysis tenutosi a Lyon nel 2013.
Steam reforming of ethanol over Co and Cu based catalysts
I.G. RossettiUltimo
2013
Abstract
Co- and Cu-based catalysts prepared by flame pyrolysis (FP) technique are proposed as possible substitutes for Ni-based catalysts, very active for the Ethanol Steam Reforming reaction, but showing poor stability towards coke formation when operating at relatively low temperature. The FP method allowed to achieve a partial incorporation of the active phase into the support, leading to high dispersion and lower reducibility. The best results were achieved with 10wt% Co/SiO2, which led to higher activity, good C balance and low CO/CO2 ratio. This was ascribed to the high initial dispersion of Co into the silica matrix, which led to available Co particles well dispersed and stable.Pubblicazioni consigliate
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