The X-ray structures of 4-amidiniumpyridine acetate, (1.H)AcO, and of cis-[Pt(1)2(PPh3)2](NO3)2 (2), as well as their IR spectra, reveal intramolecular hydrogen bonding which held together the cations and the anions. IR data suggest that this may be so also in cis-[PtCl(1)(PPh3)2](BF4) (3). In (1.H)AcO and in 2 extensive intermolecular hydrogen bonding networks span through the whole crystals
Hydrogen bonding network of 4-amidiniumpyridine acetate and PtIIbis(triphenylphosphine) complexes with 4-amidinepyridine / L. Rigamonti, S. Carlino, C. Castellano, F. Demartin, A. Pasini. - In: ZEITSCHRIFT FÜR ANORGANISCHE UND ALLGEMEINE CHEMIE. - ISSN 0044-2313. - 638:14(2012), pp. 2252-2256. [10.1002/zaac.201200256]
Hydrogen bonding network of 4-amidiniumpyridine acetate and PtIIbis(triphenylphosphine) complexes with 4-amidinepyridine
L. RigamontiPrimo
;C. Castellano;F. DemartinPenultimo
;A. PasiniUltimo
2012
Abstract
The X-ray structures of 4-amidiniumpyridine acetate, (1.H)AcO, and of cis-[Pt(1)2(PPh3)2](NO3)2 (2), as well as their IR spectra, reveal intramolecular hydrogen bonding which held together the cations and the anions. IR data suggest that this may be so also in cis-[PtCl(1)(PPh3)2](BF4) (3). In (1.H)AcO and in 2 extensive intermolecular hydrogen bonding networks span through the whole crystals
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