The solvent-dependent reassembling of a conventional dimeric [Ti-O-Ti] unit into a chainlike titanoxane under ionization conditions is reported. The titanoxane is the polymeric form of the tetrameric sequence [Ti=O-Ti-O-Ti-O=Ti] containing both the titanyl unit and the mu-oxo dimer, polymerization being achieved by a sharing of the oxygen atoms from the Schiff base ligand.
Linear Titanoxanes via the Assembling of Bridging and Terminal Oxo-Titanium(IV) Fragments / E. Gallo, E. Solari, F. Franceschi, C. Floriani, A. Chiesi Villa, C. Rizzoli. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - 34:10(1995), pp. 2495-2496.
Linear Titanoxanes via the Assembling of Bridging and Terminal Oxo-Titanium(IV) Fragments
E. GalloPrimo
;
1995
Abstract
The solvent-dependent reassembling of a conventional dimeric [Ti-O-Ti] unit into a chainlike titanoxane under ionization conditions is reported. The titanoxane is the polymeric form of the tetrameric sequence [Ti=O-Ti-O-Ti-O=Ti] containing both the titanyl unit and the mu-oxo dimer, polymerization being achieved by a sharing of the oxygen atoms from the Schiff base ligand.
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