The synthesis and the structure of the novel tri-anion, [Fe3Rh3(CO)17]3-, is reported: the metal framework of this 88 valence electron bimetallic cluster is unusual, and consists of an Fe2Rh3 trigonal bipyramid with iron and rhodium atoms in apical sites and a dangling Fe atom attached to the apical Rh.

BIMETALLIC IRON-RHODIUM CARBONYL CLUSTERS - SYNTHESIS AND X-RAY STRUCTURE OF THE NOVEL [FE3RH3(CO)17] (3-) TRI-ANION / A. CERIOTTI, R. DELLAPERGOLA, G. LONGONI, B. HEATON, F. DEMARTIN, M. MANASSERO. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 311:1-2(1986), pp. C31-C33. [10.1016/0022-328X(86)80245-5]

BIMETALLIC IRON-RHODIUM CARBONYL CLUSTERS - SYNTHESIS AND X-RAY STRUCTURE OF THE NOVEL [FE3RH3(CO)17] (3-) TRI-ANION

A. CERIOTTI;F. DEMARTIN;
1986

Abstract

The synthesis and the structure of the novel tri-anion, [Fe3Rh3(CO)17]3-, is reported: the metal framework of this 88 valence electron bimetallic cluster is unusual, and consists of an Fe2Rh3 trigonal bipyramid with iron and rhodium atoms in apical sites and a dangling Fe atom attached to the apical Rh.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/190143
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