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IRIS è il sistema di gestione integrata dei dati della ricerca (persone, progetti, pubblicazioni, attività) adottato dall'Università degli Studi di Milano.

AIR nasce in UNIMI nel 2006 con lo scopo di raccogliere, documentare e conservare le informazioni sulla produzione scientifica dell'Università degli Studi di Milano e costituisce di fatto l'Anagrafe della ricerca dell'Ateneo.

The electron transfer reaction between palladium(0) complexes and RNO compounds afforded different palladium species depending on the aromatic or aliphatic nature of R. When R = Ph a paramagnetic palladium complex 1 was isolated, whereas if R = Bu-t the palladium enolate complex 2 was the unexpected reaction product. Complex 1 reacted with methanol and CO to yield Pd(phen)(C(O)OCH3}(2) 3, which was characterised by single-crystal X-ray structure determination. Compound 3 is a probable intermediate in the reductive carbonylation reaction of organic nitro compounds catalysed by palladium complexes. Nitrobenzene is in fact carbonylated to PhNHCO2Me, by using 3 as a very efficient catalyst.

Investigation of the reactivity of palladium(0) complexes with nitroso compounds: relevance to the palladium-phenanthroline-catalysed carbonylation reactions of nitroarenes / E. Gallo, F. Ragaini, S. Cenini, F. Demartin. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 586:2(1999), pp. 190-195.

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