The solid-state linkage isomerization [Co(NH3)5NO2]Br2 double-line arrow pointing left and right [Co(NH3)5ONO]Br2 was studied, at room temperature, using the X-ray powder diffraction technique. The structure of the photochemically synthesized [Co(NH3)5-ONO]Br2 was solved in the orthorbombic space group Cmcm, with a = 10.8011(7) angstrom, b = 8.9692(6) angstrom, c = 10.6090(6) angstrom, and Z = 4, and refined by the Rietveld method, down to R(profile) = 0.119, for 4000 data points collected in the 10-90-degrees (2theta) range. The changes in the lattice parameters and the structural evolution in the course of the ONO double-line arrow pointing right NO2 linkage isomerization showed the intramolecular nature of the isomerization, with the powders remaining a monophase system at any time.
STUDY OF THE LINKAGE ISOMERIZATION [CO(NH3)5NO2]BR2[--][CO(NH3)5ONO]BR2 IN THE SOLID-STATE BY X-RAY-POWDER DIFFRACTION / N. Masciocchi, A. Kolyshev, V. Dulepov, E. Boldyreva, A. Sironi. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - 33:12(1994), pp. 2579-2585.
Titolo: | STUDY OF THE LINKAGE ISOMERIZATION [CO(NH3)5NO2]BR2[--][CO(NH3)5ONO]BR2 IN THE SOLID-STATE BY X-RAY-POWDER DIFFRACTION |
Autori: | SIRONI, ANGELO AGOSTINO DANIELE (Ultimo) |
Parole Chiave: | CRYSTALS DICHLORIDE REFINEMENT COMPLEXES NITRITE |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica |
Data di pubblicazione: | 1994 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1021/ic00090a017 |
Appare nelle tipologie: | 01 - Articolo su periodico |