The metal-hydrogen vibrational frequencies of μ-bridging hydride ligands of the rhenium cluster hydride anions [Re3(μ-H)4(CO)10]2-, [Re3(μ-H)3(CO)10]2-, [Re3(μ-H)(CO)10]-, [Re3(μ-H)3(μ-O2CH)(CO)10]- and [Re3(μ-H)3(μ3-OEt)(CO)9]- are assigned in the infrared and in the Raman (of the first four compounds) and are shown to be characteristics of the bridge environment.
VIBRATIONAL CHARACTERISTICS OF MU-BRIDGING HYDRIDE LIGANDS IN TRIANGULO RHENIUM METAL CLUSTER COMPOUNDS / C. ANSON, U. JAYASOORIYA, G. DALFONSO, P. STANGHELLINI. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 372:1(1989), pp. 85-97. [10.1016/0022-328X(89)87079-2]
VIBRATIONAL CHARACTERISTICS OF MU-BRIDGING HYDRIDE LIGANDS IN TRIANGULO RHENIUM METAL CLUSTER COMPOUNDS
G. DalfonsoPenultimo
;
1989
Abstract
The metal-hydrogen vibrational frequencies of μ-bridging hydride ligands of the rhenium cluster hydride anions [Re3(μ-H)4(CO)10]2-, [Re3(μ-H)3(CO)10]2-, [Re3(μ-H)(CO)10]-, [Re3(μ-H)3(μ-O2CH)(CO)10]- and [Re3(μ-H)3(μ3-OEt)(CO)9]- are assigned in the infrared and in the Raman (of the first four compounds) and are shown to be characteristics of the bridge environment.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
