The new [Ni13Sb2(CO)24]n- (n = 2,3,4) cluster anions have been isolated from the reaction of [Ni 6(CO)12]2- with SbCl3: their structures (n = 2,3) have been elucidated by X-ray diffraction studies and consist of Ni-centred icosahedral [Ni11Sb2(CO) 18]n- moieties which display an unexpected electron count and formally behave as 'exotic' distibine bridging ligands.
Synthesis and X-ray structure of the [Ni13Sb2(CO) 24]n- (n = 2,3,4) cluster anions containing an icosahedral [Ni11Sb2(CO)18]n- moiety behaving as a distibine ligand and displaying an unexpected electron count / V. G. Albano, F. Demartin, M. C. Iapalucci, G. Longoni, A. Sironi, V. Zanotti. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :7(1990), pp. 547-548.
Titolo: | Synthesis and X-ray structure of the [Ni13Sb2(CO) 24]n- (n = 2,3,4) cluster anions containing an icosahedral [Ni11Sb2(CO)18]n- moiety behaving as a distibine ligand and displaying an unexpected electron count |
Autori: | DEMARTIN, FRANCESCO (Secondo) SIRONI, ANGELO AGOSTINO DANIELE (Penultimo) |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica |
Data di pubblicazione: | 1990 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/C39900000547 |
Appare nelle tipologie: | 01 - Articolo su periodico |