beta-Dicarbonyl derivatives 1a-f react with fumaronitrile in the presence of catalytic amounts of [Ni(acac)(2)] or Ni(OAc)(2) to give 7-oxa-bicyclo[2,2,1]heptene derivatives 3a-f, while in similar experimental conditions, methyl malonate 1g affords the enaminodiester 5. (C) 1999 Elsevier Science B.V. All rights reserved.
Metal-catalysed reactions of beta-dicarbonyl compounds with fumaronitrile / A. Veronese, R. Callegari, C. F. Morelli, M. Basato. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - 142:3(1999), pp. 373-376.
Metal-catalysed reactions of beta-dicarbonyl compounds with fumaronitrile
C. F. MorelliPenultimo
;
1999
Abstract
beta-Dicarbonyl derivatives 1a-f react with fumaronitrile in the presence of catalytic amounts of [Ni(acac)(2)] or Ni(OAc)(2) to give 7-oxa-bicyclo[2,2,1]heptene derivatives 3a-f, while in similar experimental conditions, methyl malonate 1g affords the enaminodiester 5. (C) 1999 Elsevier Science B.V. All rights reserved.
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