The novel anion [Re 3H 3(CO) 9(μ 3-SBu t)] -, obtained by reaction of [Re 3H 4(CO) 10] - with t-butyl mercaptan, has been characterized by IR, NMR and X-ray diffraction studies. It contains an equilateral Re 3 triangle (mean ReRe 3.091 Å), with nine terminal carbonyl groups, three for each metal atom, and a triply-bridging thiolate ligand (mean ReS 2.393 Å). The three hydrides are bridging on the edges of the triangle of metal atoms. © 1982.

Reaction of the unsaturated anion [Re 3H 4(CO) 10] - with mercaptans. Synthesis and X-ray Characterization of the anion [ Re 3H 3 (CO) 9(μ 3-SBu t)] / R. Bonfichi, G. Ciani, G. D'Alfonso, P. Romiti, A. Sironi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 231:2(1982), pp. c35-c35-c37.

Reaction of the unsaturated anion [Re 3H 4(CO) 10] - with mercaptans. Synthesis and X-ray Characterization of the anion [ Re 3H 3 (CO) 9(μ 3-SBu t)]

G. Ciani
Secondo
;
G. D'Alfonso;A. Sironi
Ultimo
1982

Abstract

The novel anion [Re 3H 3(CO) 9(μ 3-SBu t)] -, obtained by reaction of [Re 3H 4(CO) 10] - with t-butyl mercaptan, has been characterized by IR, NMR and X-ray diffraction studies. It contains an equilateral Re 3 triangle (mean ReRe 3.091 Å), with nine terminal carbonyl groups, three for each metal atom, and a triply-bridging thiolate ligand (mean ReS 2.393 Å). The three hydrides are bridging on the edges of the triangle of metal atoms. © 1982.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/185614
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