The combination of lattice-constrained molecular mechanics and ab initio X-ray powder diffraction methods has enabled the full characterization of two novel members of the [{ReH(CO)4}n] family (the structure of [Re6(μ-H)6(CO)24] is depicted), thus demonstrating the existence of a unique series of inorganic analogues of (CH2)n, ranging from "ethylene" to "polyethylene".

Complete structural characterization by ab initio X-ray powder diffraction of ]Re(mu-H)(CO)(4)(n)] and [Re(mu-H)(CO)(4)(6)], inorganic analogues of polyethylene and cyclohexane / N. Masciocchi, G. D'Alfonso, L. Garavaglia, A. Sironi. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 39:24(2000), pp. 4478-4478-+.

Complete structural characterization by ab initio X-ray powder diffraction of ]Re(mu-H)(CO)(4)(n)] and [Re(mu-H)(CO)(4)(6)], inorganic analogues of polyethylene and cyclohexane

G. D'Alfonso;A. Sironi
2000

Abstract

The combination of lattice-constrained molecular mechanics and ab initio X-ray powder diffraction methods has enabled the full characterization of two novel members of the [{ReH(CO)4}n] family (the structure of [Re6(μ-H)6(CO)24] is depicted), thus demonstrating the existence of a unique series of inorganic analogues of (CH2)n, ranging from "ethylene" to "polyethylene".
hydrides oligomerizations rhenium structure elucidation
Settore CHIM/03 - Chimica Generale e Inorganica
ANGEWANDTE CHEMIE. INTERNATIONAL EDITION
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/184126
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