The combination of lattice-constrained molecular mechanics and ab initio X-ray powder diffraction methods has enabled the full characterization of two novel members of the [{ReH(CO)4}n] family (the structure of [Re6(μ-H)6(CO)24] is depicted), thus demonstrating the existence of a unique series of inorganic analogues of (CH2)n, ranging from "ethylene" to "polyethylene".
Complete structural characterization by ab initio X-ray powder diffraction of ]Re(mu-H)(CO)(4)(n)] and [Re(mu-H)(CO)(4)(6)], inorganic analogues of polyethylene and cyclohexane / N. Masciocchi, G. D'Alfonso, L. Garavaglia, A. Sironi. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 39:24(2000), pp. 4478-4478-+.
Complete structural characterization by ab initio X-ray powder diffraction of ]Re(mu-H)(CO)(4)(n)] and [Re(mu-H)(CO)(4)(6)], inorganic analogues of polyethylene and cyclohexane
G. D'AlfonsoSecondo
;A. SironiUltimo
2000
Abstract
The combination of lattice-constrained molecular mechanics and ab initio X-ray powder diffraction methods has enabled the full characterization of two novel members of the [{ReH(CO)4}n] family (the structure of [Re6(μ-H)6(CO)24] is depicted), thus demonstrating the existence of a unique series of inorganic analogues of (CH2)n, ranging from "ethylene" to "polyethylene".Pubblicazioni consigliate
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