The anion [RuIr3(CO)12]- has been isolated as one of the products from decomposition of [RuIr4(CO)15]2- in the absence of CO, and the structure of the bis(triphenylphosphine)iminium salt has been determined by X-ray diffraction. The anion is isoelectronic and isostructural with CO4(CO)12 and Rh4(CO)12, with the Ru atom located at one vertex of the metal triangle, which bears three edge-bridging carbonyls. © 1985.
Isolation of the mixed-metal carbonyl cluster anion [RuIr3(CO)9(μ-CO)3]-. Crystal structure of its bis(triphenylphosphine)iminium salt / A. Fumagalli, F. Demartin, A. Sironi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 279:3(1985), pp. c33-c33-c36.
Titolo: | Isolation of the mixed-metal carbonyl cluster anion [RuIr3(CO)9(μ-CO)3]-. Crystal structure of its bis(triphenylphosphine)iminium salt | |
Autori: | DEMARTIN, FRANCESCO (Secondo) SIRONI, ANGELO AGOSTINO DANIELE (Ultimo) | |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica | |
Data di pubblicazione: | 1985 | |
Rivista: | ||
Tipologia: | Article (author) | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/0022-328X(85)87049-2 | |
Appare nelle tipologie: | 01 - Articolo su periodico |