Oxidation of [Re3(μ-H)4(CO)10]- with CF3SO3H in acetonitrile gives the new complex Re3(μ-H)3(CO)10(NCMe)2. This contains a triangle of metal atoms with the edges bridged by the hydrides (mean ReRe 3.266 Å). The acetonitrile ligands, bound to two metals in a trans-diaxial manner, are easily replaced, giving a variety of derivatives. © 1983.
A reactive and versatile trirhenium carbonyl cluster obtained by oxidation of [re3 (μ-H)4 (CO)10]-. Synthesis, x-ray characterization and reactivity of re3 (μ-H)3 (CO)10(NCMe)2 / G. Ciani, A. Sironi, G. D'Alfonso, P. Romiti, M. Freni. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 254:3(1983), pp. C37-C37-C41.
Titolo: | A reactive and versatile trirhenium carbonyl cluster obtained by oxidation of [re3 (μ-H)4 (CO)10]-. Synthesis, x-ray characterization and reactivity of re3 (μ-H)3 (CO)10(NCMe)2 |
Autori: | CIANI, GIANFRANCO MARIA (Primo) SIRONI, ANGELO AGOSTINO DANIELE (Secondo) |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica |
Data di pubblicazione: | 1983 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/0022-328X(83)80144-2 |
Appare nelle tipologie: | 01 - Articolo su periodico |