By reaction of [Ru(CO)3(PPh3)2] with 2-nitrophenol, the deep brown ruthenium(II) complex, [Ru(OC6H 4NO-o)(OC6H4NO2-o)(CO)(PPh 3)2], has been obtained. X-Ray crystallography has shown that the complex contains a o-nitrosophenolate ligand, which co-ordinates to ruthenium in a chelating fashion through its nitroso-nitrogen and phenolic oxygen atoms.
Deoxygenation reaction of 2-nitrophenol. Synthesis and x-ray crystal structure of Ru(OC6H4NO-o)(CO)(PPh3)2 / M. Pizzotti, C. Crotti, F. Demartin. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - :4(1984), pp. 735-737. [10.1039/DT9840000735]
Deoxygenation reaction of 2-nitrophenol. Synthesis and x-ray crystal structure of Ru(OC6H4NO-o)(CO)(PPh3)2
M. PizzottiPrimo
;F. DemartinUltimo
1984
Abstract
By reaction of [Ru(CO)3(PPh3)2] with 2-nitrophenol, the deep brown ruthenium(II) complex, [Ru(OC6H 4NO-o)(OC6H4NO2-o)(CO)(PPh 3)2], has been obtained. X-Ray crystallography has shown that the complex contains a o-nitrosophenolate ligand, which co-ordinates to ruthenium in a chelating fashion through its nitroso-nitrogen and phenolic oxygen atoms.
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