Titanium silicate ETS-10 was found to be a suitable metal catalyst support, having high surface area, high ion exchange capacity and no acidic functions. In this work, ETS-10 was used as a support in preparing ruthenium supported catalyst for Fischer-Tropsch synthesis. Ru/METS-10 catalytic systems (M standing for Na or K) showed some important characteristics, as good metal dispersion and shape selectivity. Moreover, no side reactions due to acidic functions were evidenced; indeed readsorption of olefins on active metal centers was found to control the activity of the catalysts.
|Titolo:||Fischer-Tropsch synthesis on ruthenium supported ETS-10 titanium silicate catalysts|
BIANCHI, CLAUDIA LETIZIA MADDALENA (Secondo)
|Parole Chiave:||Fischer-Tropsch synthesis; olefins readsorption; ruthenium supported catalysts; titanium silicate molecular sieves|
|Settore Scientifico Disciplinare:||Settore CHIM/04 - Chimica Industriale|
|Data di pubblicazione:||1995|
|Digital Object Identifier (DOI):||10.1007/BF00817045|
|Appare nelle tipologie:||01 - Articolo su periodico|