Titanium silicate ETS-10 was found to be a suitable support for metal catalysts, having high surface area, high ion-exchange capability and no acidic functions. In this paper, the M-ETS-10 commercial form (where M stands for Na and K) was first exchanged with Co and thus tested in CO hydrogenation (Fischer-Tropsch synthesis). Moreover, the sample was also doped with small amounts of ruthenium to improve the Co reducibility, The successive catalytic tests revealed a strong increase in the CO conversion and a modification in the selectivity of the hydrocarbon fractions.
Fischer-Tropsch synthesis on Co and Co(Ru-doped) ETS- 10 titanium silicate catalysts / C.L. Bianchi, R. Carli, S. Merlotti,V. Ragaini. - In: CATALYSIS LETTERS. - ISSN 1011-372X. - 41:1-2(1996), pp. 79-82.
Fischer-Tropsch synthesis on Co and Co(Ru-doped) ETS- 10 titanium silicate catalysts
C.L. BianchiPrimo
;
1996
Abstract
Titanium silicate ETS-10 was found to be a suitable support for metal catalysts, having high surface area, high ion-exchange capability and no acidic functions. In this paper, the M-ETS-10 commercial form (where M stands for Na and K) was first exchanged with Co and thus tested in CO hydrogenation (Fischer-Tropsch synthesis). Moreover, the sample was also doped with small amounts of ruthenium to improve the Co reducibility, The successive catalytic tests revealed a strong increase in the CO conversion and a modification in the selectivity of the hydrocarbon fractions.Pubblicazioni consigliate
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