The novel hydridocarbonyl cluster compound (NEt4)[H4Re3(CO)10] has been characterized by IR, NMR and X-ray analyses. In the anion the three metal atoms form an isosceles triangle, with two long hydrogen-bridged ReRe bonds and a short doubly hydrogen-bridged ReRe double bond.

Synthesis and x-ray structure of the anion tetra-μ-hydridodecacarbonyl-triangulo-trirhenate(1-) / G. Ciani, G. D'Alfonso, M. Freni, P. Romiti, A. Sironi, A. Albinati. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 136:3(1977), pp. C49-C51.

Synthesis and x-ray structure of the anion tetra-μ-hydridodecacarbonyl-triangulo-trirhenate(1-)

G. Ciani
Primo
;
G. D'Alfonso
Secondo
;
A. Sironi
Penultimo
;
A. Albinati
Ultimo
1977

Abstract

The novel hydridocarbonyl cluster compound (NEt4)[H4Re3(CO)10] has been characterized by IR, NMR and X-ray analyses. In the anion the three metal atoms form an isosceles triangle, with two long hydrogen-bridged ReRe bonds and a short doubly hydrogen-bridged ReRe double bond.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/179643
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