Thermoelectric power determinations may significantly improve the characterization of solid electrolytes, if a convenient procedure is followed to work out the experimental results. The peculiar physical properties of a solid electrolyte are generally due to a single fastly moving ionic species: therefore, thermocells assembled with proper electrodes reversible to the mobile ion allow one to evaluate its partial molar entropy at various temperatures and, if extra information about the structure of the solid electrolyte is available, to compute other thermodynamic properties
Thermodynamic properties and thermoelectric power of solid electrolytes / A: Schiraldi, E. Pezzati, P. Baldini. - In: SOLID STATE IONICS. - ISSN 0167-2738. - 9-10:2(1983 Dec), pp. 1187-1191. [10.1016/0167-2738(83)90150-9]
Thermodynamic properties and thermoelectric power of solid electrolytes
A. SchiraldiPrimo
;
1983
Abstract
Thermoelectric power determinations may significantly improve the characterization of solid electrolytes, if a convenient procedure is followed to work out the experimental results. The peculiar physical properties of a solid electrolyte are generally due to a single fastly moving ionic species: therefore, thermocells assembled with proper electrodes reversible to the mobile ion allow one to evaluate its partial molar entropy at various temperatures and, if extra information about the structure of the solid electrolyte is available, to compute other thermodynamic properties
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