Ag 3SBr and Ag 3SI obtained through a modified preparation procedure have been investigated in the temperature range 93-573K by means of conductivity, DTA and X-ray diffraction determinations. At the phase transition temperatures the Arrhenius plot of the conductivity shows evident discontinuities, whereas in the T range where Ag 3SBr and Ag 3SI have an antiperovskitic structure this plot shows an upward curvature: for Ag 3SBr a reproducible `knee' is also observed. The general behaviour of the conductivity in the wide investigated T range suggests a direct comparison between these salts and RbAg 4I 5 which shows analogous phase transitions and discontinuities in the Arrhenius plot of the conductivity. Electronic conductivity determinations confirm that the charge transport is predominantly ionic in either compound.
Ag3SBr and Ag 3SI: Ionic conductivity of their modifications in the T range 93-573K / G. Chiodelli, A. Magistris, A. Schiraldi. - In: ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE. - ISSN 0044-3336. - 118:2(1979), pp. 177-186.
|Titolo:||Ag3SBr and Ag 3SI: Ionic conductivity of their modifications in the T range 93-573K|
SCHIRALDI, ALBERTO (Ultimo)
|Parole Chiave:||silver tiobromide; silver tioiodide; electric conductivity|
|Settore Scientifico Disciplinare:||Settore CHIM/02 - Chimica Fisica|
|Data di pubblicazione:||1979|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1524/zpch.19220.127.116.11|
|Appare nelle tipologie:||01 - Articolo su periodico|