Thermoelectric power measurements show that beta- AgI behaves as AgCl and AgBr, whereas the gamma-phase is quite different. The transport number of the interstitial Ag + in beta-AgI is evaluated from thermoelectric power and electrical conductivity data. The partial ionic entropy ( SAg(+)) gamma-AgI, estimated from thermoelectric power data is smaller than ( SAg(+)) beta-AgI, as expected from the irreversibility of the transition gamma- AgI/beta- AgI.
Thermoelectric power of beta- and gamma-AgI / A. Schiraldi. - In: ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE. - ISSN 0044-3336. - 97:5-6(1975 Sep), pp. 285-293. [10.1524/zpch.1975.97.5_6.285]
Thermoelectric power of beta- and gamma-AgI
A. SchiraldiPrimo
1975
Abstract
Thermoelectric power measurements show that beta- AgI behaves as AgCl and AgBr, whereas the gamma-phase is quite different. The transport number of the interstitial Ag + in beta-AgI is evaluated from thermoelectric power and electrical conductivity data. The partial ionic entropy ( SAg(+)) gamma-AgI, estimated from thermoelectric power data is smaller than ( SAg(+)) beta-AgI, as expected from the irreversibility of the transition gamma- AgI/beta- AgI.File in questo prodotto:
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