[Fe(en)3]2Hg2Te9, a novel tellurometalate containing a new type of Zintl ion (Hg2Te9)4-, has been synthesized from solvothermal reactions. Single-crystal X-ray diffraction analysis shows that this compounds contains one-dimensional chains of weakly bound (Hg2Te9)4- ions separated by iron tris(ethylenediamine). Not only is [Fe(en)3]2Hg2Te9 the first tellurometalate produced from solvothermal reactions, it is also the first example of an interesting structure containing a Zintl ion and transition metal complex (as counterion) in the same phase.
[Fe(en)(3)](2)(Hg2Te9): A novel tellurometalate containing one-dimensional chains of weakly bound zintl anions (Hg2Te9)(4-) / J. Li, B. Rafferty, S. Mulley, D.M. Proserpio. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - 34:26(1995), pp. 6417-6418.
Titolo: | [Fe(en)(3)](2)(Hg2Te9): A novel tellurometalate containing one-dimensional chains of weakly bound zintl anions (Hg2Te9)(4-) |
Autori: | PROSERPIO, DAVIDE MARIA (Ultimo) |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica |
Data di pubblicazione: | 1995 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1021/ic00130a002 |
Appare nelle tipologie: | 01 - Articolo su periodico |