[Fe(en)3]2Hg2Te9, a novel tellurometalate containing a new type of Zintl ion (Hg2Te9)4-, has been synthesized from solvothermal reactions. Single-crystal X-ray diffraction analysis shows that this compounds contains one-dimensional chains of weakly bound (Hg2Te9)4- ions separated by iron tris(ethylenediamine). Not only is [Fe(en)3]2Hg2Te9 the first tellurometalate produced from solvothermal reactions, it is also the first example of an interesting structure containing a Zintl ion and transition metal complex (as counterion) in the same phase.

[Fe(en)(3)](2)(Hg2Te9): A novel tellurometalate containing one-dimensional chains of weakly bound zintl anions (Hg2Te9)(4-) / J. Li, B. Rafferty, S. Mulley, D.M. Proserpio. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - 34:26(1995), pp. 6417-6418.

[Fe(en)(3)](2)(Hg2Te9): A novel tellurometalate containing one-dimensional chains of weakly bound zintl anions (Hg2Te9)(4-)

D.M. Proserpio
Ultimo
1995

Abstract

[Fe(en)3]2Hg2Te9, a novel tellurometalate containing a new type of Zintl ion (Hg2Te9)4-, has been synthesized from solvothermal reactions. Single-crystal X-ray diffraction analysis shows that this compounds contains one-dimensional chains of weakly bound (Hg2Te9)4- ions separated by iron tris(ethylenediamine). Not only is [Fe(en)3]2Hg2Te9 the first tellurometalate produced from solvothermal reactions, it is also the first example of an interesting structure containing a Zintl ion and transition metal complex (as counterion) in the same phase.
Settore CHIM/03 - Chimica Generale e Inorganica
Article (author)
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/178153
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 30
  • ???jsp.display-item.citation.isi??? 32
social impact