BF3 OEt2 mediated aldol condensations of thioester silyl ketene acetals are stereoconvergent, and exhibit high internal (anti) and relative (Cram) diastereoselectivity.
HIGH DIASTEREOSELECTIVITY IN LEWIS ACID MEDIATED ALDOL CONDENSATIONS USING THIOESTER SILYL KETENE ACETALS / C.M.A. GENNARI, A. BERNARDI, S. CARDANI, C. SCOLASTICO. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 26:6(1985), pp. 797-800.
HIGH DIASTEREOSELECTIVITY IN LEWIS ACID MEDIATED ALDOL CONDENSATIONS USING THIOESTER SILYL KETENE ACETALS
C.M.A. GENNARIPrimo
;A. BERNARDISecondo
;C. SCOLASTICOUltimo
1985
Abstract
BF3 OEt2 mediated aldol condensations of thioester silyl ketene acetals are stereoconvergent, and exhibit high internal (anti) and relative (Cram) diastereoselectivity.
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