TiCl4-mediated addition of the chiral silyl ketene acetal (2) to benzylideneaniline proceeds with high stereoselectivity to give, after cyclization, trans- β -lactam (7) in good yield and 95% e.e.

ASYMMETRIC-SYNTHESIS OF TRANS-BETA-LACTAMS THROUGH TICL4-MEDIATED ADDITION TO IMINES / C.M.A. GENNARI, I. VENTURINI, G. GISLON, G. SCHIMPERNA. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 28:2(1987), pp. 227-230.

ASYMMETRIC-SYNTHESIS OF TRANS-BETA-LACTAMS THROUGH TICL4-MEDIATED ADDITION TO IMINES

C.M.A. GENNARI
Primo
;
1987

Abstract

TiCl4-mediated addition of the chiral silyl ketene acetal (2) to benzylideneaniline proceeds with high stereoselectivity to give, after cyclization, trans- β -lactam (7) in good yield and 95% e.e.
Settore CHIM/06 - Chimica Organica
Article (author)
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/176992
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 107
  • ???jsp.display-item.citation.isi??? 117
social impact