The biosynthetic pathway to citrinin is elucidated by incorporation studies with advanced precursors, the first step of biosynthesis involves methylation of a pentaketide, followed by cyclization, reduction to the ketoaldehyde and then to the hydroxyaldehyde, dehydration, and finally oxidation of the methyl group at C(7) to a carboxy-group.
Biosynthesis of citrinin / L. Colombo, C.M.A. Gennari, C. Scolastico, F. Aragozzini, C. Merendi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :23(1980), pp. 1132-1134. [10.1039/C39800001132]
Biosynthesis of citrinin
C.M.A. Gennari;C. Scolastico;
1980
Abstract
The biosynthetic pathway to citrinin is elucidated by incorporation studies with advanced precursors, the first step of biosynthesis involves methylation of a pentaketide, followed by cyclization, reduction to the ketoaldehyde and then to the hydroxyaldehyde, dehydration, and finally oxidation of the methyl group at C(7) to a carboxy-group.
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