Substituted 2,5-(structure 1) and 2,4-(structure 2) cyclohexadiene-1,3-dicarboxylates were prepared via Birch reductive alkylation of substituted isophthalates with alkylating agents such as alkyl and allyl halides, alkyl dihalides, alpha-halocarboxylates and epoxides. A brief discussion about their reactivity and stability is presented.
Synthesis of 2,5- and 2,4-cyclohexadiene-1,3-dicarboxylates via reductive alkylation of isophthalates / P. Seneci, M. Caspani, F. Monti, L. Carrano, S. Lociuro, R. Ciabatti. - In: SYNTHETIC COMMUNICATIONS. - ISSN 0039-7911. - 27:5(1997), pp. 795-809. [10.1080/00397919708004199]
Synthesis of 2,5- and 2,4-cyclohexadiene-1,3-dicarboxylates via reductive alkylation of isophthalates
P. SeneciPrimo
;
1997
Abstract
Substituted 2,5-(structure 1) and 2,4-(structure 2) cyclohexadiene-1,3-dicarboxylates were prepared via Birch reductive alkylation of substituted isophthalates with alkylating agents such as alkyl and allyl halides, alkyl dihalides, alpha-halocarboxylates and epoxides. A brief discussion about their reactivity and stability is presented.
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