New fluorobenzene chromium dicarbonylisocyanide complexes have been synthesized and evaluated in terms of their 'in solution' reactivity towards some nucleophiles. For the first time the polymer-bound isocyanides have been found to be valuable ligands for anchoring haloareneCr(CO)3 complexes by means of their substitution for a CO group. The supported fluorobenzene complex reacted with nitrogen-nucleophiles. (C) 2000 Elsevier Science Ltd.
New polymer-bound haloarene chromium dicarbonyl isocyanide complexes: a successful study validating their use in chemistry / S. Maiorana, C. Baldoli, E. Licandro, L. Casiraghi, E. de Magistris, A. Paio, S. Provera, P. Seneci. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 41:37(2000), pp. 7271-7275.
New polymer-bound haloarene chromium dicarbonyl isocyanide complexes: a successful study validating their use in chemistry
E. Licandro;P. SeneciUltimo
2000
Abstract
New fluorobenzene chromium dicarbonylisocyanide complexes have been synthesized and evaluated in terms of their 'in solution' reactivity towards some nucleophiles. For the first time the polymer-bound isocyanides have been found to be valuable ligands for anchoring haloareneCr(CO)3 complexes by means of their substitution for a CO group. The supported fluorobenzene complex reacted with nitrogen-nucleophiles. (C) 2000 Elsevier Science Ltd.
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