New fluorobenzene chromium dicarbonylisocyanide complexes have been synthesized and evaluated in terms of their 'in solution' reactivity towards some nucleophiles. For the first time the polymer-bound isocyanides have been found to be valuable ligands for anchoring haloareneCr(CO)3 complexes by means of their substitution for a CO group. The supported fluorobenzene complex reacted with nitrogen-nucleophiles. (C) 2000 Elsevier Science Ltd.

New polymer-bound haloarene chromium dicarbonyl isocyanide complexes: a successful study validating their use in chemistry / S. Maiorana, C. Baldoli, E. Licandro, L. Casiraghi, E. de Magistris, A. Paio, S. Provera, P. Seneci. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 41:37(2000), pp. 7271-7275.

New polymer-bound haloarene chromium dicarbonyl isocyanide complexes: a successful study validating their use in chemistry

E. Licandro;P. Seneci
Ultimo
2000

Abstract

New fluorobenzene chromium dicarbonylisocyanide complexes have been synthesized and evaluated in terms of their 'in solution' reactivity towards some nucleophiles. For the first time the polymer-bound isocyanides have been found to be valuable ligands for anchoring haloareneCr(CO)3 complexes by means of their substitution for a CO group. The supported fluorobenzene complex reacted with nitrogen-nucleophiles. (C) 2000 Elsevier Science Ltd.
Settore CHIM/06 - Chimica Organica
2000
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/170806
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