Several palladacycle and platinacycle complexes have been prepared from easily available or naturally occurring indole derivatives, such as gramine and related compounds. Dimeric complexes were obtained with Pd(OAc)(2), while Pt(DMSO)(2)Cl-2 mainly afforded monomeric structures. A notable feature of these reactions was the formation of new M-C bonds between Pd or Pt and C-2 and C-3 of the indole ring. With ligands like 2-(2'-pyridyl)-1H-indoles, N-N metallacycles were generated instead: in fact new C-M bonds with the C-3 position could only form if N-substituted indoles were used. The reactivity of Pd dimeric complexes with PPh3, sym-collidine and DMAP was explored to obtain monomeric complexes. Three such compounds were prepared, one of which was characterized by X-ray diffraction. Metathetical reactions were carried out to effect a ligand exchange replacing OAc with halide ions, with the aim to synthesize mu-Cl and mu-Br bridged structures. Turning to the synthesis of hetaryl complexes, functionalization of the C-2 position on the indole ring was achieved. These complexes were prepared by substitution reactions starting from gramine and/or its alkylammonium salts. (c) 2004 Elsevier B.V. All rights reserved.
Novel cyclometallated Pd(II) and Pt(II) complexes with indole derivatives and their use as catalysts in heck reaction / G. Cravotto, F. Demartin, G. Palmisano, A. Penoni, T. Radice, S. Tollari. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 690:8(2005), pp. 2017-2026.
Novel cyclometallated Pd(II) and Pt(II) complexes with indole derivatives and their use as catalysts in heck reaction
F. DemartinSecondo
;A. Penoni;
2005
Abstract
Several palladacycle and platinacycle complexes have been prepared from easily available or naturally occurring indole derivatives, such as gramine and related compounds. Dimeric complexes were obtained with Pd(OAc)(2), while Pt(DMSO)(2)Cl-2 mainly afforded monomeric structures. A notable feature of these reactions was the formation of new M-C bonds between Pd or Pt and C-2 and C-3 of the indole ring. With ligands like 2-(2'-pyridyl)-1H-indoles, N-N metallacycles were generated instead: in fact new C-M bonds with the C-3 position could only form if N-substituted indoles were used. The reactivity of Pd dimeric complexes with PPh3, sym-collidine and DMAP was explored to obtain monomeric complexes. Three such compounds were prepared, one of which was characterized by X-ray diffraction. Metathetical reactions were carried out to effect a ligand exchange replacing OAc with halide ions, with the aim to synthesize mu-Cl and mu-Br bridged structures. Turning to the synthesis of hetaryl complexes, functionalization of the C-2 position on the indole ring was achieved. These complexes were prepared by substitution reactions starting from gramine and/or its alkylammonium salts. (c) 2004 Elsevier B.V. All rights reserved.Pubblicazioni consigliate
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