A cyclic voltammetry study of some alkoxy, amino and hydrazino carbene complexes of chromium and tungsten has been performed, affording for the first time a detailed overview on the electrochemical activity of this useful and versatile compound class, focusing on the modulating effects of both the carbene metal and substituents. The interest for the above results is also related to the possibility of using Fischer carbenes as new electrochemical active probes for labeling ‘peptide nucleic acids’, which are DNA analogues, for diagnostic purposes.

The electrochemical activity of heteroatom-stabilised Fischer-type carbene complexes / C. Baldoli, P. Cerea, L. Falciola, C. Giannini, E. Licandro, S. Maiorana, P. Mussini, D. Perdicchia. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 690:24-25(2005), pp. 5777-5787.

The electrochemical activity of heteroatom-stabilised Fischer-type carbene complexes

P. Cerea;L. Falciola;C. Giannini;E. Licandro;S. Maiorana;P. Mussini;D. Perdicchia
2005

Abstract

A cyclic voltammetry study of some alkoxy, amino and hydrazino carbene complexes of chromium and tungsten has been performed, affording for the first time a detailed overview on the electrochemical activity of this useful and versatile compound class, focusing on the modulating effects of both the carbene metal and substituents. The interest for the above results is also related to the possibility of using Fischer carbenes as new electrochemical active probes for labeling ‘peptide nucleic acids’, which are DNA analogues, for diagnostic purposes.
Fischer carbene complexes ; electrochemical activity of Fischer-type carbene complexes ; metal-modified peptide nucleic acids ; chromium and tungsten hydrazino carbene complexes ; electrochemically active probe molecules for biosensors ; voltammetric studies ofischer-type carbene complexes
Settore CHIM/01 - Chimica Analitica
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/14867
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